J.of Soc of Agri Struc, Japan.
Vol.33,No.2 September 2002, 103-111
Original:
Language: English

Effect of Removal of Hazardous Metals from Effluent of
Biological Treatment onto Chitosan using
Electrochemical Processing

Kuen-Yuan CHUANG, Chris P.NORMAN, Norio SUGIURA,
Chuanping FENG and Takaaki MAEKAWA

ABSTRACT

    An electrochernical process to remove hexavalent chromium (Cr6+) from farm effluent using chitosan membranes was examined. The farm effluent was spiked with 50mg/L Cr6+ and model solutions with 200mg/L and 50mg/L Cr6+ in pure water were filled in a treaiment chamber separated by pieces chitosan membrane thickness 15 micro-m to 25 micro-m between both the cathode chamber and the anodic chamber. A voltage of 12V was applied for a 13h period to replicate tests on the farm effluent and the model solutions. Over 98% of Cr6+ was removed from all the solutions.
    Chitosan membrane has the potential for both the adsorption and the reduction. The excess hydroxyl ions were unable to permeate through the membrane. Cornpared to various electrochemical remediation approaches, this combination approach of electrochemical treatment and adsorption onto chitosan provides many advantages such as simplicity, Iow cost, high ion rernoval efficiency, and ease of practical operation. It has significant potential for the removal of hazardous metal ions such as Cr6+ from both industrial wastewater and organic rich farm effluent.

Keywords: heavy metal, effluent, hexavalent chromium, chitosan, electrochemistry

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